You have already received some good stuff, but I'll add a little bit.
....answer.....yes, no, maybe!
Example, you have a 30-06 bolt action rifle, with a 6 power scope, shooting a customary type big game cartridge, you are hunting deer and the maximum distance is about 240 yards. Your rifle is zeroed at 200 yards. The answer would probably be, No. From the muzzle to 240 yards you bullet should strike within the kill zone of a whitetail deer. In this situation, MOA would probably be one of those terms least likely to help you harvest the deer.
Example, you have a 7mm Remington Magnum bolt action rifle, with a 6-12 power tactical/target type scope, shooting an accurate load with a dependable hunting bullet, you are hunting proghorn, sheep, goat and the maximum distance is 600 yards. Being familiar with MOA and knowing how to apply it during both load development, zeroing and hunting, may prove to be very helpful.
MOA (minute of angle) is a constant angular reference of dimensional value, which represent a specific oblique measurement at a given distance. There are hundreds of adequate explanation on the net as reference to MOA, such as mj52 has posted above.
How you hunt, where you hunt, what you hunt, will most likely better answer your question for you personally. However, it is my opinion, whether you use MOA during your hunts or not.......if you study it, learn it, fully understand it, and apply it to your preparations to hunt.....you will find benefit in the knowledge.
Many feel it is a method to measure accuracy. Not really, but we do use it often to reference accuracy. If someone tells us their rifle is an MOA shooter, that's usually means the rifle system is capable of (not withstanding shooter ability) to shoot a 5 shots group at 100 yards which measures at, or less than 1" from center-to-center of the farthest shot holes in the group. usually this means they have measured it with a tool like a caliper, tape, ruler, or even a yard stick, none of which have MOA increments on them. And, although shooting a MOA or less size group at 100 yards gives us a reference for shorter of further distances, it's not telling us what the rifle system is capable of at let's say 800 yards!
A 1 MOA shooter at 100 yards may be a 2 MOA shooter at 800 yards. Or, a 1.5 MOA shooter could be a 1 MOA shooter at 300 plus yards!!
MOA is a reference of dimensional value we can apply in various uses and be a very good benefit, or it can be relatively worthless information for some hunters. I have a good friend, a wrangler, who carries a Win 94 30-30, loads it with Silvertip factory loads, shoots coyotes and Javelinas out to 250 yards and couldn't care less about MOA doing so. I often shoot 308 out to 1,200 yards and MOA is important to me. I use it during development, calling bullet trace, and making trajectory adjustments. It's however not the only measurement reference that can be used.
Best Regards......Eagle Six